Optimizing Anti-Freezing Agent On the Properties of Portland Cement-Calcium Sulphoaluminate Cement System Based on Taguchi-Gra Method

The investigate of new cementitious system suitable for negative temperature concreting was the key way to solve the high energy consumption of traditional winter construction. In this study, the effects of three anti-freezing agents (CaCl2, NaNO2 and Li2CO3) were selected to match the Portland cement-calcium sulphoal uminate cement blended system (PC-CSA system) based on Taguchi-Gray Relational Analysis (Taguchi-GRA method). The setting time, compressive strength and freezing point were tested. The hydration products, pore structure and morphology were also analyzed to reveal the mechanism. The results showed that CaCl2 was the main parameter influencing the initial and final setting time. Whether at the early stage of continuous negative temperature curing or from negative to positive temperature curing, CaCl2 dominated the influence on the compressive strength of PC-CSA system by increasing the number of early hydration products to rapidly build up a network structure. At the later stage of continuous negative temperature curing, the influential parameter changed to NaNO2. The hydration conditions were satisfied due to the lowering of the freezing point of the liquid phase by NaNO2. The presence of Li2CO3 enhanced the promoting effect of CaCl2 on early strength. The optimal parameter combination for PC-CSA system was 1.0% CaCl2, 2.0% NaNO2 and 0.4% Li2CO3 based on Taguchi-GRA method.